Journal of the American Chemical
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2021-04-06 [ASAP] Environment of Metal–O–Fe Bonds Enabling High Activity in CO<sub>2</sub> Reduction on Single Metal Atoms and on Supported Nanoparticles Yifeng Zhu, Simuck F. Yuk, Jian Zheng, Manh-Thuong Nguyen, Mal-Soon Lee, Janos Szanyi, Libor Kovarik, Zihua Zhu, Mahalingam Balasubramanian, Vassiliki-Alexandra Glezakou, John L. Fulton, Johannes A. Lercher, Roger Rousseau, and Oliver Y. Gutiérrez
2021-04-06 [ASAP] Radical Decarboxylative Carbometalation of Benzoic Acids: A Solution to Aromatic Decarboxylative Fluorination Peng Xu, Priscila López-Rojas, and Tobias Ritter
2021-04-06 [ASAP] Leveraging Surface Siloxide Electronics to Enhance the Relaxation Properties of a Single-Molecule Magnet Maciej D. Korzyński, Zachariah J. Berkson, Boris Le Guennic, Olivier Cador, and Christophe Copéret
2021-04-05 [ASAP] Effect of Pd Coordination and Isolation on the Catalytic Reduction of O<sub>2</sub> to H<sub>2</sub>O<sub>2</sub> over PdAu Bimetallic Nanoparticles Tomas Ricciardulli, Sahithi Gorthy, Jason S. Adams, Coogan Thompson, Ayman M. Karim, Matthew Neurock, and David W. Flaherty
2021-04-05 [ASAP] Aggregation and Supramolecular Self-Assembly of Low-Energy Red Luminescent Alkynylplatinum(II) Complexes for RNA Detection, Nucleolus Imaging, and RNA Synthesis Inhibitor Screening Angela Sin-Yee Law, Lawrence Cho-Cheung Lee, Kenneth Kam-Wing Lo, and Vivian Wing-Wah Yam
2021-04-03 [ASAP] Phosphonofluoresceins: Synthesis, Spectroscopy, and Applications Joshua L. Turnbull, Brittany R. Benlian, Ryan P. Golden, and Evan W. Miller
2021-04-03 [ASAP] Enantioselective Nickel-Catalyzed Alkyne–Azide Cycloaddition by Dynamic Kinetic Resolution En-Chih Liu and Joseph J. Topczewski
2021-04-03 [ASAP] Chemical Synthesis of Phosphorylated Insulin-like Growth Factor Binding Protein 2 Bhavesh Premdjee, Asser S. Andersen, Mark Larance, Kilian W. Conde-Frieboes, and Richard J. Payne
2021-04-03 [ASAP] Stealth Fluorescence Labeling for Live Microscopy Imaging of mRNA Delivery Tom Baladi, Jesper R. Nilsson, Audrey Gallud, Emanuele Celauro, Cécile Gasse, Fabienne Levi-Acobas, Ivo Sarac, Marcel R. Hollenstein, Anders Dahlén, Elin K. Esbjörner, and L. Marcus Wilhelmsson
2021-04-03 [ASAP] Production of Carminic Acid by Metabolically Engineered <italic toggle="yes">Escherichia coli</italic> Dongsoo Yang, Woo Dae Jang, and Sang Yup Lee
2021-04-02 [ASAP] Electrostatic Control of Photoisomerization in Channelrhodopsin 2 Ruibin Liang, Jimmy K. Yu, Jan Meisner, Fang Liu, and Todd J. Martinez
2021-04-02 [ASAP] Addition to “Enantiospecific Response in Cross-Polarization Solid-State Nuclear Magnetic Resonance of Optically Active Metal Organic Frameworks” Erick M. Carreira(Editor-in-Chief, Journal of the American Chemical Society)
2021-04-02 [ASAP] Theory-Guided Synthesis of Highly Luminescent Colloidal Cesium Tin Halide Perovskite Nanocrystals Qi Liu, Jun Yin, Bin-Bin Zhang, Jia-Kai Chen, Yang Zhou, Lu-Min Zhang, Lu-Ming Wang, Qing Zhao, Jingshan Hou, Jie Shu, Bo Song, Naoto Shirahata△, Osman M. Bakr, Omar F. Mohammed, and Hong-Tao Sun
2021-04-02 [ASAP] Catalytic Carbodiimide Guanylation by a Nucleophilic, High Spin Iron(II) Imido Complex Yafei Gao, Veronica Carta, Maren Pink, and Jeremy M. Smith
2021-04-02 [ASAP] Strategies for Biomolecular Analysis and Continuous Physiological Monitoring Amanda Clifford, Jagotamoy Das, Hanie Yousefi, Alam Mahmud, Jenise B. Chen, and Shana O. Kelley
2021-04-02 [ASAP] Chemically Triggered Coalescence and Reactivity of Droplet Fibers Jing Zhao, Zehao Pan, Deborah Snyder, Howard A. Stone, and Todd Emrick
2021-04-02 [ASAP] Catalytic Enantioselective Dehydrogenative Si–O Coupling to Access Chiroptical Silicon-Stereogenic Siloxanes and Alkoxysilanes Jiefeng Zhu, Shuyou Chen, and Chuan He
2021-04-02 [ASAP] Dipnictogen f-Element Chemistry: A Diphosphorus Uranium Complex Jingzhen Du, David Hunger, John A. Seed, Jonathan D. Cryer, David M. King, Ashley J. Wooles, Joris van Slageren, and Stephen T. Liddle
2021-04-02 [ASAP] Redox Activity of Pyridine-Oxazoline Ligands in the Stabilization of Low-Valent Organonickel Radical Complexes Clifton L. Wagner, Gabriel Herrera, Qiao Lin, Chunhua T. Hu, and Tianning Diao
2021-04-01 [ASAP] Single-Atom-Substituted Mo<sub>2</sub>C<italic toggle="yes">T</italic><sub><italic toggle="yes">x</italic></sub>:Fe-Layered Carbide for Selective Oxygen Reduction to Hydrogen Peroxide: Tracking the Ev Denis A. Kuznetsov, Zixuan Chen, Paula M. Abdala, Olga V. Safonova, Alexey Fedorov, and Christoph R. Müller
2021-04-01 [ASAP] Synthesis and Thin Films of Thermally Robust Quartet (<italic toggle="yes">S</italic> = 3/2) Ground State Triradical Chan Shu, Maren Pink, Tobias Junghoefer, Elke Nadler, Suchada Rajca, Maria Benedetta Casu, and Andrzej Rajca
2021-04-01 [ASAP] Multitasking with Chemical Fuel: Dissipative Formation of a Pseudorotaxane Rotor from Five Distinct Components Amit Ghosh, Indrajit Paul, and Michael Schmittel
2021-04-01 [ASAP] Recharged Catalyst with Memristive Nitrogen Reduction Activity through Learning Networks of Spiking Neurons Gang Zhou, Tinghui Li, Rong Huang, Peifang Wang, Bin Hu, Hao Li, Lizhe Liu, and Yan Sun
2021-04-01 [ASAP] Isolation of New Colibactin Metabolites from Wild-Type <italic toggle="yes">Escherichia coli</italic> and <italic toggle="yes">In Situ</italic> Trapping of a Mature Colibactin Derivative Tao Zhou, Yuichiro Hirayama, Yuta Tsunematsu, Nanami Suzuki, Seiji Tanaka, Nahoko Uchiyama, Yukihiro Goda, Yuko Yoshikawa, Yuji Iwashita, Michio Sato, Noriyuki Miyoshi, Michihiro Mutoh, Hideki Ishikawa, Haruhiko Sugimura, Keiji Wakabayashi, and Kenji Wata
2021-03-31 [ASAP] Neutron Diffraction Study of Significant <italic toggle="yes">sp</italic><sup>3</sup> and <italic toggle="yes">sp</italic><sup>2</sup> C–H Bond Shortening in a Fluorinated Pyridinium Saccharinate Norman Lu, Vijayanath Elakkat, Joseph S. Thrasher, Xiaoping Wang, Eskedar Tessema, Ka Long Chan, Rong-Jun Wei, Tarek Trabelsi, and Joseph S. Francisco
2021-03-31 [ASAP] Tackling Solubility Issues in Organic Synthesis: Solid-State Cross-Coupling of Insoluble Aryl Halides Tamae Seo, Naoki Toyoshima, Koji Kubota, and Hajime Ito
2021-03-31 [ASAP] Revisiting Acepleiadylene: Two-Step Synthesis and π-Extension toward Nonbenzenoid Nanographene Pengcai Liu, Xing-Yu Chen, Jiawen Cao, Lukas Ruppenthal, J. Michael Gottfried, Klaus Müllen, and Xiao-Ye Wang
2021-03-31 [ASAP] Reversible C(sp<sup>3</sup>)-Si Oxidative Addition of Unsupported Organosilanes: Effects of Silicon Substituents on Kinetics and Thermodynamics Scott M. Chapp and Nathan D. Schley
2021-03-31 [ASAP] Enantioselective Hydroalkenylation of Olefins with Enol Sulfonates Enabled by Dual Copper Hydride and Palladium Catalysis Alexander W. Schuppe, James Levi Knippel, Gustavo M. Borrajo-Calleja, and Stephen L. Buchwald
2021-03-31 [ASAP] Mechanically Responsive Luminescent Polymers Based on Supramolecular Cyclophane Mechanophores Yoshimitsu Sagara, Hanna Traeger, Jie Li, Yuji Okado, Stephen Schrettl, Nobuyuki Tamaoki, and Christoph Weder
2021-03-31 [ASAP] DCAF11 Supports Targeted Protein Degradation by Electrophilic Proteolysis-Targeting Chimeras Xiaoyu Zhang, Lena M. Luukkonen, Christie L. Eissler, Vincent M. Crowley, Yu Yamashita, Michael A. Schafroth, Shota Kikuchi, David S. Weinstein, Kent T. Symons, Brian E. Nordin, Joe L. Rodriguez, Thomas G. Wucherpfennig, Ludwig G. Bauer, Melissa M. Dix, D
2021-03-31 [ASAP] Genetically Encoded Fragment-Based Discovery from Phage-Displayed Macrocyclic Libraries with Genetically Encoded Unnatural Pharmacophores Arunika I. Ekanayake, Lena Sobze, Payam Kelich, Jihea Youk, Nicholas J. Bennett, Raja Mukherjee, Atul Bhardwaj, Frank Wuest, Lela Vukovic, and Ratmir Derda
2021-03-31 [ASAP] A Copper(I)-Catalyzed Radical-Relay Reaction Enabling the Intermolecular 1,2-Alkylborylation of Unactivated Olefins Sota Akiyama, Natsuki Oyama, Tsubura Endo, Koji Kubota, and Hajime Ito
2021-03-31 [ASAP] Cobalt-Catalyzed Markovnikov-Selective Radical Hydroacylation of Unactivated Alkenes with Acylphosphonates Benxiang Zhang, Jiayan He, Yi Li, Tao Song, Yewen Fang, and Chaozhong Li
2021-03-31 [ASAP] Mechanistic Investigation of 1,2-Diol Dehydration of Paromamine Catalyzed by the Radical <italic toggle="yes">S</italic>-Adenosyl-<sc>l</sc>-methionine Enzyme AprD4 Yu-Cheng Yeh, Hak Joong Kim, and Hung-wen Liu
2021-03-31 [ASAP] Buffered Coordination Modulation as a Means of Controlling Crystal Morphology and Molecular Diffusion in an Anisotropic Metal–Organic Framework Kristen A. Colwell, Megan N. Jackson, Rodolfo M. Torres-Gavosto, Sudi Jawahery, Bess Vlaisavljevich, Joseph M. Falkowski, Berend Smit, Simon C. Weston, and Jeffrey R. Long
2021-03-31 [ASAP] 3D Heteronuclear Magnetization Transfers for the Establishment of Secondary Structures in SARS-CoV-2-Derived RNAs Jihyun Kim, Mihajlo Novakovic, Sundaresan Jayanthi, Adonis Lupulescu, Eriks Kupce, J. Tassilo Grün, Klara Mertinkus, Andreas Oxenfarth, Christian Richter, Robbin Schnieders, Julia Wirmer-Bartoschek, Harald Schwalbe, and Lucio Frydman
2021-03-31 [ASAP] Remarkably Efficient Iridium Catalysts for Directed C(sp<sup>2</sup>)–H and C(sp<sup>3</sup>)–H Borylation of Diverse Classes of Substrates Md Emdadul Hoque, Mirja Md Mahamudul Hassan, and Buddhadeb Chattopadhyay
2021-03-31 [ASAP] Single-Event Spectroscopy and Unravelling Kinetics of Covalent Domains Based on Cyclobutane Mechanophores Brandon H. Bowser, Shu Wang, Tatiana B. Kouznetsova, Haley K. Beech, Bradley D. Olsen, Michael Rubinstein, and Stephen L. Craig
2021-03-30 [ASAP] Hydrogen Atom Transfer-Driven Enantioselective Minisci Reaction of Amides Rupert S. J. Proctor, Padon Chuentragool, Avene C. Colgan, and Robert J. Phipps
2021-03-30 [ASAP] Cobalt-Catalyzed Intermolecular C–H Amidation of Unactivated Alkanes Jeonghyo Lee, Seongho Jin, Dongwook Kim, Soon Hyeok Hong, and Sukbok Chang
2021-03-30 [ASAP] Dirigent Proteins Guide Asymmetric Heterocoupling for the Synthesis of Complex Natural Product Analogues Stacie S. Kim and Elizabeth S. Sattely
2021-03-30 [ASAP] Creating an Aligned Interface between Nanoparticles and MOFs by Concurrent Replacement of Capping Agents Yang Li, Wei-Shang Lo, Furui Zhang, Xiaomeng Si, Lien-Yang Chou, Xiao-Yuan Liu, Benjamin P. Williams, Yu-Hsiu Li, Seung-Hea Jung, Yu-Shen Hsu, Fu-Siang Liao, Fa-Kuen Shieh, Mariam N. Ismail, Wenyu Huang, and Chia-Kuang Tsung
2021-03-30 [ASAP] The Antiviral Enzyme, Viperin, Activates Protein Ubiquitination by the E3 Ubiquitin Ligase, TRAF6 Ayesha M. Patel and E. Neil G. Marsh
2021-03-30 [ASAP] Photon Upconversion in a Glowing Metal–Organic Framework Indranil Roy, Subhadip Goswami, Ryan M. Young, Itai Schlesinger, Mohammad Rasel Mian, Alan E. Enciso, Xuan Zhang, Jessica E. Hornick, Omar K. Farha, Michael R. Wasielewski, Joseph T. Hupp, and J. Fraser Stoddart
2021-03-27 [ASAP] Ozone Decomposition by a Manganese-Organic Framework over the Entire Humidity Range Zhi-Bing Sun, Ya-Nan Si, Shu-Na Zhao, Qian-You Wang, and Shuang-Quan Zang
2021-03-27 [ASAP] A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane Alexander J. Bukvic, Arron L. Burnage, Graham J. Tizzard, Antonio J. Martínez-Martínez, Alasdair I. McKay, Nicholas H. Rees, Bengt E. Tegner, Tobias Krämer, Heather Fish, Mark R. Warren, Simon J. Coles, Stuart A. Macgregor, and Andrew S. Weller
2021-03-27 [ASAP] Block-Random Copolymer-Micellization-Mediated Formation of Polymeric Patches on Gold Nanoparticles Yiqun Yang, Chenglin Yi, Xiaozheng Duan, Qi Wu, Yan Zhang, Jing Tao, Wenhao Dong, and Zhihong Nie
2021-03-27 [ASAP] Illuminating Stannylation Kyoka Sakamoto, Yuki Nagashima, Chao Wang, Kazunori Miyamoto, Ken Tanaka, and Masanobu Uchiyama
2021-03-27 [ASAP] Correction to “Enhancement of van der Waals Interlayer Coupling through Polar Janus MoSSe” Kunyan Zhang, Yunfan Guo, Qingqing Ji, Ang-Yu Lu, Cong Su, Hua Wang, Alexander A. Puretzky, David B. Geohegan, Xiaofeng Qian, Shiang Fang, Efthimios Kaxiras, Jing Kong, and Shengxi Huang
2021-03-26 [ASAP] A Strategy Based on the Enzyme-Catalyzed Polymerization Reaction of Asp-Phe-Tyr Tripeptide for Cancer Immunotherapy Qiu-Ling Zhang, Diwei Zheng, Xue Dong, Pei Pan, Si-Min Zeng, Fan Gao, Si-Xue Cheng, and Xian-Zheng Zhang
2021-03-26 [ASAP] Sequence-Selective Decapeptide Synthesis by the Parallel Operation of Two Artificial Molecular Machines Javier Echavarren, Malcolm A. Y. Gall, Adrian Haertsch, David A. Leigh, Justin T. J. Spence, Daniel J. Tetlow, and Chong Tian
2021-03-26 [ASAP] Short-Range Ordered Iridium Single Atoms Integrated into Cobalt Oxide Spinel Structure for Highly Efficient Electrocatalytic Water Oxidation Jieqiong Shan, Chao Ye, Shuangming Chen, Tulai Sun, Yan Jiao, Lingmei Liu, Chongzhi Zhu, Li Song, Yu Han, Mietek Jaroniec, Yihan Zhu, Yao Zheng, and Shi-Zhang Qiao
2021-03-26 [ASAP] Charging a Negatively Curved Nanographene and Its Covalent Network Yiqun Zhang, Yikun Zhu, Danni Lan, Sai Ho Pun, Zheng Zhou, Zheng Wei, Ying Wang, Hung Kay Lee, Chao Lin, Jiangpeng Wang, Marina A. Petrukhina, Quan Li, and Qian Miao
2021-03-26 [ASAP] Distinct Carrier Transport Properties Across Horizontally vs Vertically Oriented Heterostructures of 2D/3D Perovskites Ming-Yu Kuo, Natalia Spitha, Matthew P. Hautzinger, Pei-Lun Hsieh, Jing Li, Dongxu Pan, Yuzhou Zhao, Lih-Juann Chen, Michael H. Huang■, Song Jin, Yung-Jung Hsu, and John C. Wright
2021-03-26 [ASAP] Nickel–Sulfonate Mode of Substrate Binding for Forward and Reverse Reactions of Methyl-SCoM Reductase Suggest a Radical Mechanism Involving Long-Range Electron Transfer Anjali Patwardhan, Ritimukta Sarangi, Bojana Ginovska, Simone Raugei, and Stephen W. Ragsdale
2021-03-26 [ASAP] Steric-Effects-Directed B–H Bond Activation of <italic toggle="yes">para</italic>-Carboranes Peng-Fei Cui, Xin-Ran Liu, Shu-Ting Guo, Yue-Jian Lin, and Guo-Xin Jin
2021-03-26 [ASAP] CuH-Catalyzed Regio- and Enantioselective Hydrocarboxylation of Allenes: Toward Carboxylic Acids with Acyclic Quaternary Centers Sheng Feng and Stephen L. Buchwald
2021-03-26 [ASAP] Correction to “How Do Local Reactivity Descriptors Shape the Potential Energy Surface Associated with Chemical Reactions? The Valence Bond Delocalization Perspective” Thijs Stuyver, Frank De Proft, Paul Geerlings, and Sason Shaik
2021-03-26 [ASAP] Tunable Methacrylamides for Covalent Ligand Directed Release Chemistry Rambabu N. Reddi, Efrat Resnick, Adi Rogel, Boddu Venkateswara Rao, Ronen Gabizon, Kim Goldenberg, Neta Gurwicz, Daniel Zaidman, Alexander Plotnikov, Haim Barr, Ziv Shulman, and Nir London
2021-03-26 [ASAP] Concise Synthesis of 9,11-Secosteroids Pinnigorgiols B and E Xinghui Li, Zeliang Zhang, Huafang Fan, Yinlong Miao, Hailong Tian, Yucheng Gu, and Jinghan Gui
2021-03-26 [ASAP] Direct α-Acylation of Alkenes via N-Heterocyclic Carbene, Sulfinate, and Photoredox Cooperative Triple Catalysis Kun Liu and Armido Studer
2021-03-26 [ASAP] Enhanced Ion Sieving of Graphene Oxide Membranes via Surface Amine Functionalization Yijun Qian, Jing Shang, Dan Liu, Guoliang Yang, Xungai Wang, Cheng Chen||, Liangzhi Kou, and Weiwei Lei
2021-03-26 [ASAP] Anion Exchange of Ruddlesden–Popper Lead Halide Perovskites Produces Stable Lateral Heterostructures Chris R. Roy, Dongxu Pan, Yining Wang, Matthew P. Hautzinger, Yuzhou Zhao, John C. Wright, Zihua Zhu, and Song Jin
2021-03-26 [ASAP] Double-Helix Supramolecular Nanofibers Assembled from Negatively Curved Nanographenes Kenta Kato⬡, Kiyofumi Takaba, Saori Maki-Yonekura, Nobuhiko Mitoma, Yusuke Nakanishi, Taishi Nishihara, Taito Hatakeyama□, Takuma Kawada□, Yuh Hijikata■, Jenny Pirillo■, Lawrence T. Scott, Koji Yonekura△, Yasutomo Segawa▽▼, and Kenichiro Itami■
2021-03-26 [ASAP] Molecularly Imprinted Synthetic Glucosidase for the Hydrolysis of Cellulose in Aqueous and Nonaqueous Solutions Xiaowei Li, Milad Zangiabadi, and Yan Zhao
2021-03-26 [ASAP] Photocatalytic Dehydroxymethylative Arylation by Synergistic Cerium and Nickel Catalysis Yuegang Chen, Xin Wang, Xu He, Qing An, and Zhiwei Zuo
2021-03-26 [ASAP] Alternating Heterochiral Supramolecular Copolymerization Michihisa Ueda, Tsubasa Aoki, Takayoshi Akiyama, Takayuki Nakamuro, Keitaro Yamashita, Haruaki Yanagisawa, Osamu Nureki, Masahide Kikkawa, Eiichi Nakamura, Takuzo Aida, and Yoshimitsu Itoh
2021-03-26 [ASAP] Genetic Code Expansion: Inception, Development, Commercialization Miglena Manandhar, Eugene Chun, and Floyd E. Romesberg
2021-03-26 [ASAP] Enantioselective Allylation of Alkenyl Boronates Promotes a 1,2-Metalate Rearrangement with 1,3-Diastereocontrol Colton R. Davis, Irungu K. Luvaga, and Joseph M. Ready
2021-03-26 [ASAP] Synergy between Photoluminescence and Charge Transport Achieved by Finely Tuning Polymeric Backbones for Efficient Light-Emitting Transistor Dafei Yuan, Mohammad A. Awais, Valerii Sharapov, Xunshan Liu, Andriy Neshchadin, Wei Chen, and Luping Yu
2021-03-26 [ASAP] Expedient Total Syntheses of Pladienolide-Derived Spliceosome Modulators Derek Rhoades, Arnold L. Rheingold, Bert W. O’Malley, and Jin Wang
2021-03-26 [ASAP] Biomolecular Condensates under Extreme Martian Salt Conditions Zamira Fetahaj, Lena Ostermeier, Hasan Cinar, Rosario Oliva, and Roland Winter
2021-03-26 [ASAP] Record Enhancement of Curie Temperature in Host–Guest Inclusion Ferroelectrics Xian-Jiang Song, Tie Zhang, Zhu-Xiao Gu, Zhi-Xu Zhang, Da-Wei Fu, Xiao-Gang Chen, Han-Yue Zhang, and Ren-Gen Xiong
2021-03-26 [ASAP] Diarylethene-Powered Light-Induced Folding of Supramolecular Polymers Takuya Fukushima, Kenta Tamaki, Atsushi Isobe, Takashi Hirose, Nobutaka Shimizu, Hideaki Takagi, Rie Haruki, Shin-ichi Adachi, Martin J. Hollamby, and Shiki Yagai
2021-03-26 [ASAP] Coordination of LiH Molecules to Mo≣Mo Bonds: Experimental and Computational Studies on Mo<sub>2</sub>LiH<sub>2</sub>, Mo<sub>2</sub>Li<sub>2</sub>H<sub>4</sub>, and Mo<sub>6</sub Marina Perez-Jimenez, Natalia Curado, Celia Maya, Jesus Campos, Jesus Jover, Santiago Alvarez, and Ernesto Carmona
2021-03-26 [ASAP] Dissipative Gated and Cascaded DNA Networks Zhixin Zhou, Yu Ouyang, Jianbang Wang, and Itamar Willner
2021-03-26 [ASAP] Two-Dimensional Barriers for Probing Conformational Shifts in Macrocycles Shinya Kobori, Sungjoon Huh, Solomon D. Appavoo, and Andrei K. Yudin
2021-03-26 [ASAP] Spotlights on Recent <italic toggle="yes">JACS</italic> Publications ACS Contributing Correspondents
2021-03-26 [ASAP] Ligand Conformational Flexibility Enables Enantioselective Tertiary C–B Bond Formation in the Phosphonate-Directed Catalytic Asymmetric Alkene Hydroboration Huiling Shao, Suman Chakrabarty, Xiaotian Qi, James M. Takacs, and Peng Liu▽
2021-03-26 [ASAP] Pd-Catalyzed <italic toggle="yes">ipso</italic>,<italic toggle="yes">meta</italic>-Dimethylation of <italic toggle="yes">ortho</italic>-Substituted Iodoarenes via a Base-Controlled C–H Activation Cascade with Dim Zhuo Wu, Feng Wei, Bin Wan, and Yanghui Zhang
2021-03-26 [ASAP] Structure and Functionality of an Alkylated Li<sub><italic toggle="yes">x</italic></sub>Si<sub><italic toggle="yes">y</italic></sub>O<sub><italic toggle="yes">z</italic></sub> Shira Haber, Rosy, Arka Saha, Olga Brontvein, Raanan Carmieli, Arava Zohar, Malachi Noked, and Michal Leskes
2021-03-26 [ASAP] Molecular Design of Chemically Fueled Peptide–Polyelectrolyte Coacervate-Based Assemblies Fabian Späth, Carsten Donau, Alexander M. Bergmann, Moritz Kränzlein, Christopher V. Synatschke, Bernhard Rieger, and Job Boekhoven
2021-03-26 [ASAP] Allele-Specific RNA Knockdown with a Biologically Stable and Catalytically Efficient XNAzyme Kim Nguyen, Yajun Wang, Whitney E. England, John C. Chaput, and Robert C. Spitale
2021-03-26 [ASAP] Selective CRAF Inhibition Elicits Transactivation Charles W. Morgan, Ian L. Dale, Andrew P. Thomas, James Hunt, and Jason W. Chin
2021-03-26 [ASAP] Cell Surface Engineering Using DNAzymes: Metal Ion Mediated Control of Cell–Cell Interactions Ruo-Can Qian, Ze-Rui Zhou, Weijie Guo, Yuting Wu, Zhenglin Yang, and Yi Lu
2021-03-26 [ASAP] Design of BET Inhibitor Bottlebrush Prodrugs with Superior Efficacy and Devoid of Systemic Toxicities Farrukh Vohidov, Jannik N. Andersen, Kyriakos D. Economides, Michail V. Shipitsin, Olga Burenkova, James C. Ackley, Bhavatarini Vangamudi, Hung V.-T. Nguyen, Nolan M. Gallagher, Peyton Shieh, Matthew R. Golder, Jenny Liu, William K. Dahlberg, Deborah J. C
2021-03-26 [ASAP] Redox Modifications in the Biosynthesis of Alchivemycin A Enable the Formation of Its Key Pharmacophore Hong Jie Zhu, Bo Zhang, Lan Wang, Wen Wang, Shuang He Liu, Yasuhiro Igarashi, Ghader Bashiri, Ren Xiang Tan, and Hui Ming Ge
2021-03-26 [ASAP] Amplification of Dissymmetry Factors in π-Extended [7]- and [9]Helicenes Zijie Qiu, Cheng-Wei Ju, Lucas Frédéric, Yunbin Hu, Dieter Schollmeyer, Grégory Pieters, Klaus Müllen, and Akimitsu Narita
2021-03-26 [ASAP] Auger-Assisted Electron Transfer between Adjacent Quantum Wells in Two-Dimensional Layered Perovskites Zixi Yin, Jing Leng, Shiping Wang, Guijie Liang, Wenming Tian, Kaifeng Wu, and Shengye Jin
2021-03-26 [ASAP] Copper(I)-Catalyzed Regioselective Asymmetric Addition of 1,4-Pentadiene to Ketones Feng Zhong, Zhi-Zhou Pan, Si-Wei Zhou, Hai-Jun Zhang, and Liang Yin
2021-03-26 [ASAP] DNA-Based Dynamic Mimicry of Membrane Proteins for Programming Adaptive Cellular Interactions Jin Li, Kanyu Xun, Liyan Zheng, Xueyu Peng, Liping Qiu, and Weihong Tan
2021-03-26 [ASAP] Molecular Rationale for Partitioning between C–H and C–F Bond Activation in Heme-Dependent Tyrosine Hydroxylase Yifan Wang, Ian Davis, Inchul Shin, Hui Xu, and Aimin Liu
2021-03-26 [ASAP] Strongly Polarized Iridium<sup>δ−</sup>–Aluminum<sup>δ+</sup> Pairs: Unconventional Reactivity Patterns Including CO<sub>2</sub> Cooperative Reductive Cleavage Léon Escomel, Iker Del Rosal, Laurent Maron, Erwann Jeanneau, Laurent Veyre, Chloé Thieuleux, and Clément Camp
2021-03-26 [ASAP] Nanoparticle Shape Determines Dynamics of Targeting Nanoconstructs on Cell Membranes Priscilla Choo, Tingting Liu, and Teri W. Odom
2021-03-26 [ASAP] Interaction of Photogenerated Spin Qubit Pairs with a Third Electron Spin in DNA Hairpins Emmaline R. Lorenzo, Jacob H. Olshansky, Daniel S. D. Abia, Matthew D. Krzyaniak, Ryan M. Young, and Michael R. Wasielewski
2021-03-26 [ASAP] Improving the Efficiency of Quantum Dot Sensitized Solar Cells beyond 15% via Secondary Deposition Han Song, Yu Lin, Zhengyan Zhang, Huashang Rao, Wenran Wang, Yueping Fang, Zhenxiao Pan, and Xinhua Zhong
2021-03-26 [ASAP] Ruthenium-Catalyzed, Chemoselective and Regioselective Oxidation of Polyisobutene Liye Chen, Katerina G. Malollari|, Adam Uliana, and John F. Hartwig
2021-03-26 [ASAP] Long-Lived Triplet Excited State in a Heterogeneous Modified Carbon Nitride Photocatalyst Adam J. Rieth, Yangzhong Qin, Benjamin C. M. Martindale, and Daniel G. Nocera
2021-03-26 [ASAP] Semiconducting and Metallic [5,5] Fullertube Nanowires: Characterization of Pristine D<sub>5h</sub>(1)-C<sub>90</sub> and D<sub>5d</sub>(1)-C<sub>100</sub> Steven Stevenson, Xiaoyang Liu, D. Mathew Sublett, Jr., Ryan M. Koenig, Tiffany L. Seeler, Katelyn R. Tepper, Hannah M. Franklin, Xiaoling Wang, Rong Huang, Xu Feng, Kevin Cover, Diego Troya, Narasimhamurthy Shanaiah, Robert J. Bodnar, and Harry C. Dorn

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